CobaltMaghrebV1, Main, Exploration, bibRecord, 000255

catena-Poly[[bis[4-(dimethylamino)pyridine-κN1]cobalt(II)]-di-μ-azido-κ4N1:N3]

Identifieur interne : 000255 ( Main/Exploration ); précédent : 000254; suivant : 000256

catena-Poly[[bis[4-(dimethylamino)pyridine-κN1]cobalt(II)]-di-μ-azido-κ4N1:N3]

Auteurs : Fatiha Guenifa [Algérie] ; Ouahida Zeghouan [Algérie] ; Nasreddine Hadjadj [Algérie] ; Lamia Bendjeddou [Algérie] ; Hocine Merazig [Algérie]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2013.

RBID : PMC:3588528

Abstract

The title layered polymer, [Co(N₃)₂(C₇H₁₀N₂)₂]_n, contains Co^II, azide and 4-(dimethylamino)pyridine (4-DMAP) species with site symmetries m2m, 2 and m, respectively. The Co²⁺ ion adopts an octahedral coordination geometry in which four N atoms from azide ligands lie in the equatorial plane and two 4-DMAP N atoms occupy the axial positions. The Co^II atoms are connected by two bridging azide ligands, resulting in a chain parallel to the c axis.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588528

DOI: 10.1107/S1600536813005205
PubMed: 23476514
PubMed Central: 3588528

Affiliations:

Algérie

Le document en format XML

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-Poly[[bis[4-(dimethylamino)pyridine-κ<italic>N</italic>
<sup>1</sup>
]cobalt(II)]-di-μ-azido-κ<sup>4</sup>
<italic>N</italic>
<sup>1</sup>
:<italic>N</italic>
<sup>3</sup>
]</title>
<author><name sortKey="Guenifa, Fatiha" sort="Guenifa, Fatiha" uniqKey="Guenifa F" first="Fatiha" last="Guenifa">Fatiha Guenifa</name>
<affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Campus Chaabet Ersas, Université Constantine I, 25000 Constantine,<country>Algeria</country>
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<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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<author><name sortKey="Zeghouan, Ouahida" sort="Zeghouan, Ouahida" uniqKey="Zeghouan O" first="Ouahida" last="Zeghouan">Ouahida Zeghouan</name>
<affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Campus Chaabet Ersas, Université Constantine I, 25000 Constantine,<country>Algeria</country>
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<country xml:lang="fr">Algérie</country>
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</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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<author><name sortKey="Bendjeddou, Lamia" sort="Bendjeddou, Lamia" uniqKey="Bendjeddou L" first="Lamia" last="Bendjeddou">Lamia Bendjeddou</name>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main"><italic>catena</italic>
-Poly[[bis[4-(dimethylamino)pyridine-κ<italic>N</italic>
<sup>1</sup>
]cobalt(II)]-di-μ-azido-κ<sup>4</sup>
<italic>N</italic>
<sup>1</sup>
:<italic>N</italic>
<sup>3</sup>
]</title>
<author><name sortKey="Guenifa, Fatiha" sort="Guenifa, Fatiha" uniqKey="Guenifa F" first="Fatiha" last="Guenifa">Fatiha Guenifa</name>
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<country xml:lang="fr">Algérie</country>
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<author><name sortKey="Zeghouan, Ouahida" sort="Zeghouan, Ouahida" uniqKey="Zeghouan O" first="Ouahida" last="Zeghouan">Ouahida Zeghouan</name>
<affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Campus Chaabet Ersas, Université Constantine I, 25000 Constantine,<country>Algeria</country>
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<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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<author><name sortKey="Bendjeddou, Lamia" sort="Bendjeddou, Lamia" uniqKey="Bendjeddou L" first="Lamia" last="Bendjeddou">Lamia Bendjeddou</name>
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<author><name sortKey="Merazig, Hocine" sort="Merazig, Hocine" uniqKey="Merazig H" first="Hocine" last="Merazig">Hocine Merazig</name>
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<series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title>
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<front><div type="abstract" xml:lang="en"><p>The title layered polymer, [Co(N<sub>3</sub>
)<sub>2</sub>
(C<sub>7</sub>
H<sub>10</sub>
N<sub>2</sub>
)<sub>2</sub>
]<sub><italic>n</italic>
</sub>
, contains Co<sup>II</sup>
, azide and 4-(dimethylamino)pyridine (4-DMAP) species with site symmetries <italic>m</italic>
2<italic>m</italic>
, 2 and <italic>m</italic>
, respectively. The Co<sup>2+</sup>
 ion adopts an octahedral coordination geometry in which four N atoms from azide ligands lie in the equatorial plane and two 4-DMAP N atoms occupy the axial positions. The Co<sup>II</sup>
 atoms are connected by two bridging azide ligands, resulting in a chain parallel to the <italic>c</italic>
 axis.</p>
</div>
</front>
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<affiliations><list><country><li>Algérie</li>
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<tree><country name="Algérie"><noRegion><name sortKey="Guenifa, Fatiha" sort="Guenifa, Fatiha" uniqKey="Guenifa F" first="Fatiha" last="Guenifa">Fatiha Guenifa</name>
</noRegion>
<name sortKey="Bendjeddou, Lamia" sort="Bendjeddou, Lamia" uniqKey="Bendjeddou L" first="Lamia" last="Bendjeddou">Lamia Bendjeddou</name>
<name sortKey="Hadjadj, Nasreddine" sort="Hadjadj, Nasreddine" uniqKey="Hadjadj N" first="Nasreddine" last="Hadjadj">Nasreddine Hadjadj</name>
<name sortKey="Merazig, Hocine" sort="Merazig, Hocine" uniqKey="Merazig H" first="Hocine" last="Merazig">Hocine Merazig</name>
<name sortKey="Zeghouan, Ouahida" sort="Zeghouan, Ouahida" uniqKey="Zeghouan O" first="Ouahida" last="Zeghouan">Ouahida Zeghouan</name>
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Serveur d'exploration sur le cobalt au Maghreb

catena-Poly[[bis[4-(dimethylamino)pyridine-κN1]cobalt(II)]-di-μ-azido-κ4N1:N3]

catena-Poly[[bis[4-(dimethylamino)pyridine-κN1]cobalt(II)]-di-μ-azido-κ4N1:N3]

Source :

Abstract

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	Serveur d'exploration sur le cobalt au Maghreb
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Serveur d'exploration sur le cobalt au Maghreb

catena-Poly[[bis­[4-(dimethyl­amino)­pyridine-κN1]cobalt(II)]-di-μ-azido-κ4N1:N3]

catena-Poly[[bis­[4-(dimethyl­amino)­pyridine-κN1]cobalt(II)]-di-μ-azido-κ4N1:N3]

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Abstract

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catena-Poly[[bis[4-(dimethylamino)pyridine-κN1]cobalt(II)]-di-μ-azido-κ4N1:N3]

catena-Poly[[bis[4-(dimethylamino)pyridine-κN1]cobalt(II)]-di-μ-azido-κ4N1:N3]